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Organic Chemistry II

 

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Lecture Notes & Assignment


Syllabus of 2010 Spring
Note: The WebCT is upon running as of 5:00 pm, January 20, 2010, and you can access the Blackboard from Friday.

1. Introduction

2. Mechanism Review       Exercise Questions       Answers to Exercise Questions

3. Infrared Spectroscopy & Mass Spectroscopy        IR Spectra       Stretch & Bending

    Alcohol Fragmentation       Alkyl Halide Fragmentation       Answers to Homework

4. NMR Spectroscopy       NMR Signal Splitting       NMR Assignment       Answers to Homework

5. Ethers, Epoxides, & Sulfides       Common Terms       Ether Nomenclature1 2      

    Ether Fragmentation Ring Opening of Epoxides       Answers to Homework       Exercises

6. Conjugated Systems, Orbital Symmetry & UV Spectroscopy       Bicyclic Compounds

    Cycloaddition Reaction       Resonance Contributor       Localized & Delocalized Electron

    Molecular Orbital Orbital Overlaping       Kinetic & Thermodynamic Products              

    Answers to Homework       Exercises

7. Aromatic Compounds Common Terms       Orbital Description       Aromaticity              

    Acidity       Substitution       Answers to Homework       Exercises

8. Reactions of Aromatic Compounds       Donation of Electron to Benzene       Electrophilic

    Substitution Substitution Intermediate       Withdrawal of Electron from Benzene            

    Multiple Synthesis of Benzene Derivatives       Answers to Homework       Exercises

9. Ketones & Aldehydes       Nomenclature       Common Terms for Addition      

    Addition to Carbonyl Compounds       Imine & Oxime       Wittig Reaction                    

    Wolff-Kishner Reaction Fragmentation of Ketones       Answers to Homework       Exercises

10. Amines Synthesis       Common Heterocycles       Lone-Pair Electrons on Nitrogen           

    Basic Sites in Heterocycles       Hofmann Elimination       Sandmeyer Reaction      Exercises

    Answers to Homework

11. Carboxylic Acids       Fischer Esterification       Answers to Homework       Exercises

12. Carboxylic Acid Derivatives       Nomenclature       Terms of Acid                       

      Conversions betweenCarboxyl Reduction       Free Energy Diagram 

      Mechanism of Hydrolysis       Answers to Homework       Exercises

13. Condensations & Alpha Substitution of Carbonyl Compounds       Carboxylic Derivative

      Common Reaction       a-Halogenated Carbonyls       Acetoacetic Ester Synthesis

      Aldol Reaction       Claisen Reaction       Malonic Ester Synthesis       Robinson Annulation

      Retrosynthetic Analysis Retrosynthesis       Answers to Homework       Exercises

14. Carbohydrates & Nucleic Acids       D & L Notation       Carbohydrate Terms

     Glycosidic Linkage       Mechanism Translation       Answers to Homework       Exercises

15. Amino Acids, Peptides & Proteins       Carboxypeptidase       Electrophoresis  

     Merrifield Solid Synthesis       Answers to Homework       Exercises

16. Lipids       Isoprene Units in Terpenes       Steroids       Answers to Homework       Exercises

17. Synthetic Polymers       Repeating Units in Addition Polymerization       Repeating Units in Step-Growth Polymerization

      Answers to Homework       Exercises

Dynamic Illustration of Reaction Mechanisms

You can access many reaction details about the above contents from this link.